If you are downloading your ACS data from the Census web portal "data.census.gov" - you should use Chrome and download using a ZIP file. This will ensure that your data comes with GEO/FIPS codes. That should allow you to have the codes to join. If you are using shapefiles (TIGER/line), depending on what you are doing, you could instead download the cartographic boundary files, which use less memory, and join to our data quite easily. You can contact me directly if you need more guidance or help. David Kraiker, Data Dissemination Specialist, david.j.kraiker@census.gov